Venezuela claim a surprise 1-0 win over Colombia in Rancagua thanks to Jose Salomon Rondon's goal on the hour mark.
Colombia's side included Real Madrid's James Rodriguez, Chelsea's Juan Cuadrado, Monaco's Radamel Falcao and Arsenal's David Ospina, but they could not break down their stubborn opponents.
Colombia now face Brazil in Group C, who defeated Peru 2-1.
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