England will play Germany and Chile in Wembley friendlies in November as part of their World Cup preparations.
Roy Hodgson's team, who beat Poland 2-0 on Tuesday to qualify for Brazil 2014, will face Chile on 15 November before meeting three-time World Cup winners Germany four days later.
Both opponents have also qualified for next summer's tournament.
England have not played Germany since losing 4-1 to them in the second round of the 2010 World Cup finals.
Denmark are likely to visit in March for another pre-World Cup game.